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Phthalo blue

A strong, synthetic blue pigment made from copper phthalocyanine

portion of unit cell for CuPc
Photo: Smokefoot, CC BY-SA 4.0, via Wikimedia Commons

Phthalo blue is a synthetic blue pigment, known for its intense colour, high tinting strength, and resistance to light and chemicals. First produced in the 1930s, it is widely used in paints, inks, plastics, and artists’ materials for its stability and brilliant blue shade.

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  • First made in 1927 as a synthetic pigment
  • Known for high lightfastness and tinting strength
  • Used in artists’ paints, inks, plastics, and cosmetics
  • Non-toxic and resistant to acids and alkalis
  • Standard blue for printing and packaging industries

What colour is Phthalo blue?

Phthalo blue is a bright, crystalline blue pigment made in laboratories, not found in nature. Its colour is a strong, vivid blue with a slight greenish bias, and it appears as a fine blue powder. The pigment is valued for its high tinting strength, meaning a small amount can colour a large quantity of material. It is transparent and stains easily, making it popular for glazing techniques in painting. Phthalo blue stands out from other blues for its intensity, stability, and resistance to fading or chemical change.

Where does Phthalo blue come from?

The pigment was first discovered in 1927 as a by-product during chemical reactions involving copper and organic compounds. Its commercial production began in the 1930s in Great Britain, Germany, and later the United States, under names like Monastral Blue. The name 'phthalo blue' comes from its chemical group, phthalocyanines, which are synthetic dyes. The pigment quickly became popular for its brilliant colour and durability, replacing older blue pigments in many uses.

How is Phthalo blue made?

Phthalo blue is produced by heating phthalonitrile or a mix of phthalic anhydride and urea with a copper salt at high temperatures. The process can use solvents or be solvent-free, with the latter now preferred for environmental reasons. The resulting copper phthalocyanine forms a stable, crystalline powder that is insoluble in water and most solvents. The pigment can be further modified to create dyes for textiles and other uses.

Where Phthalo blue is used

This pigment is widely used in artists’ paints, printing inks, plastics, and coatings. Its stability and strength make it a standard blue in the packaging industry and a staple on artists’ palettes. Phthalo blue is also found in everyday products like hair conditioners, soaps, sunscreens, and tattoo inks. In art, it is known for its transparency and ability to create bright, clean mixes. It is also used in research for electronics and solar cells due to its chemical properties.

Blue around the world

What the blue family means from country to country.

🇩🇪 Germany

The blue flower, die blaue Blume, comes from a novel by Novalis. It became the emblem of German Romanticism and stands for longing for what cannot be reached.

Love and desireNostalgiaSource: Blue flower
🇩🇪 Germany

Prussian blue, one of the first modern synthetic pigments, was made by accident in Berlin in the early 1700s. It later coloured the coats of the Prussian army.

Nature and renewalSource: Prussian blue
🇯🇵 Japan

Indigo dyeing, called aizome, clothed ordinary people in deep blue through the Edo period. The men's national football team plays in blue and is nicknamed Samurai Blue.

Festival and celebrationPrideSource: Japan national football team
🇦🇫 Afghanistan

Lapis lazuli has been mined in the mountains of Badakhshan for more than six thousand years. Ground to powder it gave ultramarine, the costliest blue in European painting.

Royalty and powerSacred and holyAweSource: Lapis lazuli
🇦🇫 Afghanistan

The chadari is a full-length covering for women with a mesh panel over the eyes. In Kabul and the north it is most often a light blue.

Protection and healingSource: Burqa
🇦🇲 Armenia

The blue band of the flag stands for the wish of the Armenian people to live under peaceful skies. The red above it is for the highlands and the struggle to survive.

Politics and protestHopeSource: Flag of Armenia

More on what blue means

Shades and relatives of Phthalo blue

Phthalo blue comes in several forms, mainly the alpha and beta crystalline phases, which differ in stability and how the pigment disperses. There are also related pigments, such as phthalocyanine green (made by treating phthalo blue with chlorine) and other metal phthalocyanines like cobalt or aluminium versions. The pigment is sometimes confused with other synthetic blues but is distinct for its strong tinting power and greenish undertone.

Colours that go with Phthalo blue

ComplementaryIts opposite on the wheel
AnalogousIts neighbours
TriadicThree evenly spaced
Split complementaryEither side of its opposite
White text 14.69:1passes AAA
Black text 1.43:1fails

Harmonies are worked out from the value #000F89. Contrast ratios follow the WCAG 2 formula.

Questions people ask about Phthalo blue

What colour is phthalo blue?

Phthalo blue is a vivid, strong blue with a slight greenish tint. It is known for its brightness and intensity, making it a popular choice for artists and industry.

Where does the name phthalo blue come from?

The name comes from its chemical group, phthalocyanines, which are synthetic dyes. The pigment contains copper at its core.

How is phthalo blue made?

It is made by heating phthalonitrile or a mix of phthalic anhydride and urea with a copper salt at high temperatures, resulting in a stable blue powder.

What is phthalo blue used for?

It is widely used in artists’ paints, printing inks, plastics, coatings, and even cosmetics and hair products due to its stability and strong colour.

Is phthalo blue safe to use?

Phthalo blue is considered non-toxic and is not known to cause harm to humans, fish, or plants. It is stable and does not break down easily.

Good reading and sources

Where this page comes from

The facts on this page come from the Wikipedia article "Copper phthalocyanine", written by its contributors and used under the CC BY-SA 4.0 licence, and from its Wikidata record (CC0). Rang rewrote the text in its own words, with AI assistance, and compares every page with the article to make sure no passage is copied. It may be reused under the same CC BY-SA 4.0 licence with a link back.

It may contain mistakes. The swatch is an approximation: named colours are not fixed standards, and every screen shows them a little differently. If something is wrong, tell us. Last refreshed 2026-10-03.

Photo credits on this page

The small pictures above come from Wikimedia Commons under free licences. Some are cropped to fit.

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